This research article published by Elsevier Ltd, 2021Phosphorus (P) is a vital plant macronutrient required for plant growth which usually available in limited amount. P availability for plant uptake in highly weathered soil is controlled by soil erosion and high fixation. The availability of P applied from fertilizers depend on the soil pH, soil sorption capacity (PSC) and P saturation status (PSD), which determines P storage, losses, fixation, and additional P to be added with minimal loss to the environment. PSC and PSD are agro-environmental indicators used to estimate P availability and P loss to the environment. However, PSC and PSD of agricultural soils had been never studied in Tanzanian soils. This study was conducted to assess and estimate P availability, PSC and PSD and the risks of P losses in tropical soils from Usangu basin popular for paddy farming. In total, 198 soil samples from 10 paddy irrigation schemes were collected (November-December 2019) and analyzed for inherent P (P), metal oxides of Aluminium (Al ), iron (Fe ), and calcium (Ca ) as main PSC and PSD determinant. The determined concentrations were in range of; P 014.9-974.69 mg/kg, Al 234.56-3789.36 mg/kg, Fe 456.78-2980.23 mg/kg, and Ca 234.67-973.34 mg/kg. Estimated PSC ranged 5.62-34.85 mmol/kg with a mean value of 14.14 mmol/kg corresponding to high status, ensuring high P holding capacity for plant uptake. However, some soils had very low PSC creating a risk of P loss to environment. Among soils, the estimated PSD ranged from 0.01 to 17.57% and was below (<24%), indicating low P loss risks to surface and groundwater, however, some soils were observed to have PSD above 15% which correspond to a critical degree of phosphate saturation of 25% in a watershed using oxalate extraction method. Therefore some sites were associated with high P loss to the environment, immediate and precautionary actions for sustainable P management to increase productivity, environmental safety and sustainability are needed to be in place.