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Photoactivemetal oxide systems capable of reducing non-biodegradable pollutants are highly needed heterogeneous
catalysts for environmental purification. Most of the currently available heterogeneous catalysts are
obtained from complicated synthetic routes using expensive and perhaps hazardous precursors. The present
study reports a novel sol–gelmethod to synthesize pure TiO2 and ZrO2–TiO2 samples using titanium oxychloride
as TiO2 precursor and zirconyl nitrate hydrate as a ZrO2 source in the presence of the surfactant. The ratio of Zr-to-
Ti was controlled between 0.75 and 3.2 to evaluate the effect of the amount of ZrO2 in the composites. Consequently,
the precipitates were calcined at different temperatures to investigate the effect of removing the
template at different sintering temperatures. The physico-chemical properties of the samples were examined
by SEM, HRTEM, DT-TGA, XRD, FTIR, XRF, EDX, nitrogen gas physisorption and UV–visible diffusive reflectance
spectrometry analyses. These analyses revealed that the crystallization, dispersion, particle size and shape of
the samples are critically dependent upon the calcination temperatures and Zr-to-Ti ratios. Abnormal grain
growth (AGG) was unexpectedly observed in the samples calcined at higher temperatures (≤800 °C). Comparisons
of the activities of the samples toward decolorization of methylene blue indicated that the photocatalytic
efficiencies of the composites with Zr/Ti ≤ 2.2 were superior to that of pure TiO2. |
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