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Investigation into the Humidity Dependence Glass Transition of Cellulosic Fibres

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dc.creator Haule, Liberato Venant
dc.date 2016-05-29T18:08:11Z
dc.date 2016-05-29T18:08:11Z
dc.date 2015-07-08
dc.date.accessioned 2018-03-27T08:37:19Z
dc.date.available 2018-03-27T08:37:19Z
dc.identifier http://hdl.handle.net/20.500.11810/2311
dc.identifier.uri http://hdl.handle.net/20.500.11810/2311
dc.description Haule, L. V (2015), “Investigation into the Humidity Dependence Glass Transition of Cellulosic Fibres”. The 10th Annual Sida Regional Collaboration Conference”,8th -10th July, 2015, Maputo, Mozambique
dc.description The glass transition temperature at different relative humidity for cotton, lyocell and viscose fibres was investigated by Differential Scanning Calorimetric (DSC) technique. The relationship between glass transition temperature and moisture content of the materials was investigated by using the Fox -equation. It was observed and concluded that, the Fox-equation can be used to determine non-water-accessible fraction in materials, which may be equal to crystalline fraction. Taking into account crystallinity effects in cellulosic materials, the Fox- equation can well be used for quantifying the relationship between glass transition temperature and moisture content for all materials. It was found that, the glass transition of each of the investigated material in dry state was above 200°C. Furthermore, investigations were carried out to compare the performance of large volume stainless steel pans with low volume aluminium pans used for holding the samples. It was observed that, the aluminium pans give a better heat signal, besides lower costs, when compared to large volume stainless steel pans. The challenges related to the use of the two types of pan and ways to overcome the challenges has been recommended.
dc.description Tanzania Gatsby Trust, Lenzing Fibers
dc.language en
dc.publisher Sida
dc.subject cellulose
dc.subject glass transition
dc.subject fox theory
dc.title Investigation into the Humidity Dependence Glass Transition of Cellulosic Fibres
dc.type Conference Paper


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