| dc.creator |
Yu, Baoyi |
|
| dc.creator |
Hamad, Fatma B. |
|
| dc.creator |
Leus, Karen |
|
| dc.creator |
Lyapkov, Alex A. |
|
| dc.creator |
Van Hecke, Kristof |
|
| dc.creator |
Verpoort, Francis |
|
| dc.date |
2016-06-18T18:13:19Z |
|
| dc.date |
2016-06-18T18:13:19Z |
|
| dc.date |
2015 |
|
| dc.date.accessioned |
2018-03-27T08:54:33Z |
|
| dc.date.available |
2018-03-27T08:54:33Z |
|
| dc.identifier |
Yu, B., Hamad, F.B., Leus, K., Lyapkov, A.A., Van Hecke, K. and Verpoort, F., 2015. Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity. Journal of Organometallic Chemistry, 791, pp.148-154. |
|
| dc.identifier |
http://hdl.handle.net/20.500.11810/2577 |
|
| dc.identifier |
10.1002/chin.201551058 |
|
| dc.identifier.uri |
http://hdl.handle.net/20.500.11810/2577 |
|
| dc.description |
We report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2inwhich R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidenecatalysts were analyzed by means of IR, elementa l analysis, NMR and single crystal X-Ray diffractionanalysis. Furthermore, the catalytic performance of these new complexes was examined in dif ferentmetathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activ-ity in comparison with the commercially available catalyst 3a |
|
| dc.language |
en |
|
| dc.publisher |
Elsevier |
|
| dc.subject |
Olefin metathesis |
|
| dc.subject |
Ruthenium |
|
| dc.subject |
Indenylidene |
|
| dc.subject |
Homogeneous |
|
| dc.subject |
Catalysis |
|
| dc.title |
Alkyl Group-Tagged Ruthenium Indenylidene Complexes: Synthesis, Characterization and Metathesis Activity |
|
| dc.type |
Journal Article, Peer Reviewed |
|