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Significantly enhanced energy storage density of NNT ceramics using aliovalent Dy3+ Dopant

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dc.creator Emmanuel, Marwa
dc.creator Hao, Hua
dc.creator Liu, Hanxing
dc.creator Jan, Abdullah
dc.creator Alresheedi, Faisal
dc.date 2021-05-10T08:53:25Z
dc.date 2021-05-10T08:53:25Z
dc.date 2021
dc.date.accessioned 2022-10-20T13:09:27Z
dc.date.available 2022-10-20T13:09:27Z
dc.identifier Emmanuel, M., Hao, H., Liu, H., Jan, A., & Alresheedi, F. (2021). ACS Sustainable Chemistry & Engineering 9 (17), 5849-5859 DOI: 10.1021/acssuschemeng.0c08714
dc.identifier DOI: https://doi.org/10.1021/acssuschemeng.0c08714
dc.identifier http://hdl.handle.net/20.500.12661/2998
dc.identifier.uri http://hdl.handle.net/20.500.12661/2998
dc.description Abstract. Full text article available at: https://doi.org/10.1021/acssuschemeng.0c08714
dc.description Sodium niobate (NN)-based lead-free ceramic DyxNa1–x(Nb0.9Ta0.1)O3 denoted as (DNNT) x = 0, 0.05, 0.1, 0.2, and 0.3 was synthesized via a conventional solid-state method to achieve bulk lead-free dielectric ceramics having an improved energy storage capability that can conceivably be used in pulsed power technology. The addition of Dy3+ broadened the phase transition peak, thereby strengthening the relaxor properties of the DNNT ceramic materials. The sample’s microstructure was explored using a scanning electron microscope, and its corresponding phase structure via X-ray diffraction (XRD). A systematic study was carried out for energy storage properties of 0.2 mol of Dy3+ (DNNT20) where a recoverable energy storage density (Wrec) of 4.61 J cm–3 with a breakdown strength (BDS) of 478 kV cm–1 and an energy storage efficiency (η) of ≈84% were achieved. Additionally, the DNNT20 ceramics displayed comparatively reasonable temperature stability (20–140 °C), excellent frequency stability (0.1–100 Hz), and also fast charge–discharge speed (≤0.5 μs). Thus, the DNNT20 ceramic materials can be of probable use for future energy storage applications.
dc.language en
dc.publisher American Chemical Society
dc.subject Dielectric properties
dc.subject Lead-free
dc.subject Charge−discharge properties
dc.subject Particle size distribution
dc.subject Energy storage
dc.subject Sodium niobate
dc.subject Power technology
dc.title Significantly enhanced energy storage density of NNT ceramics using aliovalent Dy3+ Dopant
dc.type Article


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