The Synthesis, Spectroscopy and X-ray Single Crystal Structure of Catena-[(μ-anacardato)-copper(II)bipyridine][Cu2{(μ-O2CC6H3(o-OH)(o-C15H31)}4(NC5H5)2]

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dc.creatorMalik, Azad
dc.creatorO'Brien, Paul
dc.creatorTuna, Floriana
dc.creatorPritchard, Robin G.
dc.creatorBuchweishaija, Joseph
dc.creatorKimambo, Elianaso
dc.creatorMubofu, Egid B.
dc.date2016-06-15T20:51:13Z
dc.date2016-06-15T20:51:13Z
dc.date2013-08
dc.date.accessioned2018-03-27T08:54:23Z
dc.date.available2018-03-27T08:54:23Z
dc.descriptionFull text can be accessed at http://pubs.rsc.org/en/content/articlehtml/2013/dt/c3dt51634b
dc.descriptionHydrogenation of crude anacardic acid gave a transparent crystalline product on recrystallization. When reacted with copper nitrate in the presence of pyridine it produced green crystals of a pyridine adduct of a dimeric copper(ii) anacardate with the copper acetate structure. The X-ray single crystal structures of both anacardic acid and the copper complex were determined. Magnetic studies have confirmed strong antiferromagnetic coupling between copper(ii) centre in the dimer. The exchange coupling constant was determined to be J = -324 cm(-1). The EPR spectra of the polycrystalline product are consistent with spin S = 1. The zero-field splitting parameter and g tensor values are |D| = 0.36 cm(-1), g|| = 2.36 and g⊥ = 2.06.
dc.identifierMalik, M.A., O'Brien, P., Tuna, F., Pritchard, R., Buchweishaija, J., Kimambo, E. and Mubofu, E.B., 2013. The synthesis, spectroscopy and X-ray single crystal structure of catena-[(μ-anacardato)-copper (ii) bipyridine][Cu 2 {(μ-O 2 CC 6 H 3 (o-OH)(o-C 15 H 31)} 4 (NC 5 H 5) 2]. Dalton Transactions, 42(40), pp.14438-14444.
dc.identifierhttp://hdl.handle.net/20.500.11810/2460
dc.identifier10.1039/c3dt51634b
dc.identifier.urihttp://hdl.handle.net/20.500.11810/2460
dc.languageen
dc.titleThe Synthesis, Spectroscopy and X-ray Single Crystal Structure of Catena-[(μ-anacardato)-copper(II)bipyridine][Cu2{(μ-O2CC6H3(o-OH)(o-C15H31)}4(NC5H5)2]
dc.typeJournal Article

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