Alkyl Group-Tagged Ruthenium Indenylidene Complexes: Synthesis, Characterization and Metathesis Activity

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dc.creatorYu, Baoyi
dc.creatorHamad, Fatma B.
dc.creatorLeus, Karen
dc.creatorLyapkov, Alex A.
dc.creatorVan Hecke, Kristof
dc.creatorVerpoort, Francis
dc.date2016-06-18T18:13:19Z
dc.date2016-06-18T18:13:19Z
dc.date2015
dc.date.accessioned2018-03-27T08:54:33Z
dc.date.available2018-03-27T08:54:33Z
dc.descriptionWe report on the synthesis of ruthenium indenylidene catalysts [RuCl2(3-R-1-indenylidene)(PCy3)2inwhich R is iso-propyl (7a), tert-butyl (7b) or cyclohexyl (7c)]. The obtained alkyl tagged indenylidenecatalysts were analyzed by means of IR, elementa l analysis, NMR and single crystal X-Ray diffractionanalysis. Furthermore, the catalytic performance of these new complexes was examined in dif ferentmetathesis reactions: ring-closing metathesis (RCM), ring-closing ene-yne metathesis (RCEYM), ring-opening metathesis polymerization (ROMP) and cross metathesis (CM), exhibiting a comparable activ-ity in comparison with the commercially available catalyst 3a
dc.identifierYu, B., Hamad, F.B., Leus, K., Lyapkov, A.A., Van Hecke, K. and Verpoort, F., 2015. Alkyl group-tagged ruthenium indenylidene complexes: Synthesis, characterization and metathesis activity. Journal of Organometallic Chemistry, 791, pp.148-154.
dc.identifierhttp://hdl.handle.net/20.500.11810/2577
dc.identifier10.1002/chin.201551058
dc.identifier.urihttp://hdl.handle.net/20.500.11810/2577
dc.languageen
dc.publisherElsevier
dc.subjectOlefin metathesis
dc.subjectRuthenium
dc.subjectIndenylidene
dc.subjectHomogeneous
dc.subjectCatalysis
dc.titleAlkyl Group-Tagged Ruthenium Indenylidene Complexes: Synthesis, Characterization and Metathesis Activity
dc.typeJournal Article, Peer Reviewed

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