Geological and hydro-geochemical assessment of fluorine around mount Meru, northern Tanzania
| dc.creator | Makoba, Edikafubeni Edson | |
| dc.date | 2020-10-06T10:42:11Z | |
| dc.date | 2020-10-06T10:42:11Z | |
| dc.date | 2020-03 | |
| dc.description | A Dissertation Submitted in Partial Fulfilment of the Requirements for the Degree of Doctor of Philosophy in Hydrology and Water Resources Engineering of the Nelson Mandela African Institution of Science and Technology | |
| dc.description | Areas around Mt. Meru are among the areas in Tanzania where climate change, population growth and high fluoride levels in much of the water sources lower availability of water for domestic and agricultural uses. Therefore, a study was conducted to review Holocene climatic records in relation to fluoride variation, assess fluorine source rocks and minerals, its dispersion patterns and hydrological characteristics of the aquifers in relation to the quality of water around Mt. Meru. Holocene climatic records indicated high concentration of fluoride in glacier at Mt. Kilimanjaro during dry phases (eg. 8.2 and 4.0 ka) and early Holocene, most likely derived from dried shallow lakes. High fluorine concentrations were obtained in rocks (mean= 0.39%, n=68) and soils (mean= 0.35%, n=32) with maximum values of 1.91% and 1.78% respectively. F was high in andesitic rocks (mean= 0.71%, n= 13) relative to other weakly fractionated rocks suggesting incompatibility of F in early stages of fractional crystallization. It was also high, about 3 folds in rocks relative to equivalent soils. The main contributing minerals in the order of decreasing are sphene, hornblende, apatite and biotite. Rock-equivalent soils relationship indicated that rock texture is the main factor controlling the release of fluorine from rocks to soils with more ions dissolved in groundwater in areas dominated by the relatively soluble materials (lahars). Mobility of fluorine in soils and water was found to be largely controlled by soil type, soil chemistry and groundwater movement. The dominant water type was found to be Na-K-HCO 3 with high Na + and K being largely released from nepheline and clinopyroxene minerals. Overall, excluding highest fluoride values in leeward lakes (mean=567 mg/l, n=3), fluoride was also high in other water sources (mean=10 mg/l, n=97). Lowest values were in windward springs (mean=1.3 mg/l, n=21). The quality of water for domestic and agriculture uses was moderate in the order of springs > streams > boreholes > dug wells > lakes. Resistivity survey revealed freshwater aquifers characterized by the resistivity between 35 and 60 Ωm hosted in weathered mafic volcanic rocks, tuffs and breccias and aquifers of low groundwater quality exhibiting resistivity between 15 and 25 Ωm hosted in lahars. It is further revealed that there is a strong negative correlation between aquifer resistivity with both Electrical Conductivity and fluoride in the corresponding groundwater. Groundwater Potential Index Map which serves as a guide for further groundwater development has been developed using integrated data. It is recommended to conduct leaching experiments and microprobe analysis for fluoride bearing minerals, assessing mobility of fluoride from soil to plants, levels in plants and livestock, protection and conservation of water sources. + | |
| dc.format | application/pdf | |
| dc.identifier | https://doi.org/10.58694/20.500.12479/953 | |
| dc.language | en | |
| dc.publisher | NM-AIST | |
| dc.rights | Attribution-NonCommercial-ShareAlike 4.0 International | |
| dc.rights | http://creativecommons.org/licenses/by-nc-sa/4.0/ | |
| dc.subject | Research Subject Categories::NATURAL SCIENCES | |
| dc.title | Geological and hydro-geochemical assessment of fluorine around mount Meru, northern Tanzania | |
| dc.type | Article |