Bidentate Schiff Base Ruthenium Complexes as Precursors of Homogeneous and Immobilized Catalysts

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dc.creatorVerpoort, Francis
dc.creatorYu, Baoyi
dc.creatorHamad, Fatma B.
dc.creatorVelazquez, Heriberto D.
dc.creatorLuo, Zhixiong
dc.date2016-06-18T18:15:05Z
dc.date2016-06-18T18:15:05Z
dc.date2013
dc.date.accessioned2018-03-27T08:54:36Z
dc.date.available2018-03-27T08:54:36Z
dc.descriptionFull text can be accessed at http://hdl.handle.net/1854/LU-4119567
dc.descriptionThe paper presents an overview of the work conducted in our group on the synthesis of a novel class of homogeneous and immobilized Ru-complexes containing Schiff bases as O, N-bidentate ligands benefiting from a versatile, quite general and thoroughly exemplified two-step procedure. The new Ru-complexes with improved stability incorporate a variety of Schiff bases, associated with traditional inorganic and organic ligands such as chloride, phosphanes, arenes, cyclodienes, NHC etc., and different carbenes (alkylidene, vinylidene, allenylidene and indenylidene). By a proper choice of the Schiff base, useful physical and chemical properties of the derived Ru-complexes could be induced resulting in tunable catalytic activity for metathesis and related processes. A pertinent example is the latency of selected Schiff base Ru catalysts which by becoming active only under specific conditions (heat or acid activation) are ideal for industrial applications, e.g. reaction injection molding processes. The synthetic approaches that are critically discussed in this chapter have led to a diversity of Ru-complexes of which several members have risen to the rank of commercial catalysts.
dc.identifierVerpoort, F., Yu, B., Hamad, F.B. and Diaz, H., 2013. Bidentate Schiff Base Ruthenium Complexes as Precursors of Homogeneous and Immobilized Catalysts. Advances in Organic Synthesis, 3, p.3.
dc.identifier9781608055876
dc.identifierhttp://hdl.handle.net/20.500.11810/2582
dc.identifier10.2174/9781608054688113030003
dc.identifier.urihttp://hdl.handle.net/20.500.11810/2582
dc.languageen
dc.publisherBentham Science
dc.subjectIsomerization
dc.subjectVinyl ester synthesis
dc.subjectAtom transfer radical polymerization
dc.subjectKharash addition
dc.subjectCross metathesis
dc.subjectLatent catalyst
dc.subjectRing opening metathesis
dc.subjectRing closing metathesis
dc.subjectOlefin Metathesis
dc.subjectHeterogeneous catalysis
dc.subjectSchiff base ligands
dc.subjecthomogeneous catalysis
dc.subjectruthenium hydrides
dc.subjectRuthenium arenes
dc.subjectRuthenium indenylidenes
dc.subjectRuthenium vinylidenes
dc.subjectRuthenium allenylidenes
dc.subjectRuthenium carbenes
dc.subjectOrganometallic chemistry
dc.subjectRuthenium
dc.titleBidentate Schiff Base Ruthenium Complexes as Precursors of Homogeneous and Immobilized Catalysts
dc.typeBook chapter

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