Characterization of Hydrolytic Degradation of Polylactic acid/Rice Hulls Composites in Water at Different Temperatures

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dc.creatorNdazi, Bwire S.
dc.creatorKarlssion, S.
dc.date2016-03-11T11:05:41Z
dc.date2016-03-11T11:05:41Z
dc.date2011
dc.date.accessioned2018-03-27T08:36:47Z
dc.date.available2018-03-27T08:36:47Z
dc.description. Hydrolytic degradations of polylactic acid/rice hulls (PLA/RH) composites with various rice hulls contents due to water absorptions at 23, 51 and 69°C were investigated by studying the thermal properties, chemical composition, molecular weight, and morphology of the degraded products. The results have attested that the stability of PLA/RH composites in water depends slightly on rice hulls contents but it is significantly influenced by water temperature. Water absorption in 30 days at 23°C was between 0.87 and 9.25% depending on rice hull contents. However, at thermophilic temperatures, the water absorption and degradation of these products were increased significantly. Saturations were achieved in less than 25 and 9 days at 51°C and 69°C, respectively, while hydrolytic degradation was demonstrated by an increase in fragility and development of crystallinity. At 69°C, there were significant reductions of the decomposition and glass transition temperatures of the polymer by 13°C. These changes were associated with the reduction of the molecular weight of PLA from 153.1 kDa to !10.7 kDa due to hydrolysis of its ester group.
dc.identifierNdazi, B.S. and Karlsson, S., 2011. Characterization of hydrolytic degradation of polylactic acid/rice hulls composites in water at different temperatures. Express Polym Lett, 5, pp.119-131.
dc.identifierhttp://hdl.handle.net/123456789/868
dc.identifier10.3144/expresspolymlett.2011.13
dc.identifier.urihttp://hdl.handle.net/123456789/2741
dc.languageen
dc.publisherExpress Polym Lett
dc.subjectbiodegradable polymers
dc.subjectpolylactic acid
dc.subjectrice hulls
dc.subjecthydrolytic degradation
dc.subjectmolecular weight
dc.titleCharacterization of Hydrolytic Degradation of Polylactic acid/Rice Hulls Composites in Water at Different Temperatures
dc.typeJournal Article

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Department of Mechanical and Industrial Engineering