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The water uptake of poly(tetrahydrofurfuryl methacrylate)

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dc.creator Riggs, P. D.
dc.creator Braden, M.
dc.creator Tilbrook, D. A.
dc.creator Swai, Hulda
dc.creator Clarke, R. L.
dc.creator Patel, M. P.
dc.date 2019-10-16T07:34:39Z
dc.date 2019-10-16T07:34:39Z
dc.date 1999-03
dc.date.accessioned 2022-10-25T09:20:58Z
dc.date.available 2022-10-25T09:20:58Z
dc.identifier https://doi.org/10.1016/S0142-9612(98)00188-4
dc.identifier http://dspace.nm-aist.ac.tz/handle/123456789/489
dc.identifier.uri http://hdl.handle.net/123456789/95330
dc.description Research Article published by Elsevier Volume 20, Issue 5, March 1999
dc.description Poly(tetrahydrofurfuryl methacrylate) possesses some unique characteristics with respect to its biocompatibility and behaviour in water. The water uptake is high (>70%) and very slow (over 3 yr), but the material remains rigid throughout the process. The mechanism behind the uptake is in two stages; an initial Fickian stage, then as the matrix approaches saturation (about 3 wt%) a second clustering mechanism takes over. The rate of uptake of the second stage of the uptake is controlled by creep (or stress relaxation), and the chemical potential driving the uptake from clustering of the furfuryl rings of the polymer. If clustering or the creep is prevented (by appropriate co-polymerisation) the polymer behaves in an ideal, Fickian manner.
dc.format application/pdf
dc.language en
dc.publisher Elsevier
dc.subject Water absorption
dc.subject Poly(tetrahydrofurfuryl methacrylate)
dc.subject Water absorption
dc.title The water uptake of poly(tetrahydrofurfuryl methacrylate)
dc.type Article


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