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Preparation and Characterization of Biogenic Chitosan-Hydroxyapatite Composite: Application in Defluoridation

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dc.creator Wagutu, Agatha
dc.creator Machunda, Revocatus
dc.creator Jande, Yusufu
dc.date 2020-03-31T09:30:12Z
dc.date 2020-03-31T09:30:12Z
dc.date 2018-02-20
dc.date.accessioned 2022-10-25T09:24:40Z
dc.date.available 2022-10-25T09:24:40Z
dc.identifier https://doi.org/10.1557/adv.2018.206
dc.identifier https://dspace.nm-aist.ac.tz/handle/20.500.12479/696
dc.identifier.uri http://hdl.handle.net/123456789/95659
dc.description This research article published by Cambridge University Press, Volume 3 Issue 36, 2018
dc.description In Northern Tanzania, high levels of fluoride in community drinking water supply is recognized as one of the major public health concern, the problem is further ameliorated by presence Escherichia coli and fecal coliform bacteria in surface water and shallow wells. Efforts to decontaminate the water involve mostly the use of low efficient bone char for fluoride removal without disinfecting the pathogens. To address this problem, a robust adsorbent which is capable of removing fluoride and microbes simultaneously with minimal diverse impact on the treated water is necessary. Here we highlight development of composite material developed from recycling of crustacean biomass waste from sea food industry. Chitosan polymer, isolated from prawns shell was composited with crab shell derived brushite (CaHPO4.2H2O) to form chitosan-hydroxyapatite composite. XRD and FT-IR analysis confirmed transformation of brushite phases into hydroxyapatite and formation hybrid composite. Fluoride adsorption tests were performed in batch mode to evaluate effectiveness. Defluoridation capacity of up to 6.4 mg/g in field water containing fluoride concentration of 5-70 mg/L was achieved. The best performance was observed with fluoride concentration of 10 mg/L and below. Apart from fluoride removal, the composite also reduced color tint and microbes from surface water samples. The pH of the treated water in most samples remained around 6.5-8.5, which is acceptable for drinking water.
dc.format application/pdf
dc.language en
dc.publisher Cambridge University Press
dc.subject Infrared (IR) spectroscopy
dc.subject X-ray diffraction (XRD)
dc.title Preparation and Characterization of Biogenic Chitosan-Hydroxyapatite Composite: Application in Defluoridation
dc.type Article


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