| dc.creator |
Kyobe, J. W. P. |
|
| dc.creator |
J. W.M. P. |
|
| dc.creator |
Akwilapo, Leonard D. |
|
| dc.creator |
Parmena, D. |
|
| dc.date |
2016-07-11T14:51:03Z |
|
| dc.date |
2016-07-11T14:51:03Z |
|
| dc.date |
2009-12 |
|
| dc.date.accessioned |
2018-03-27T08:54:47Z |
|
| dc.date.available |
2018-03-27T08:54:47Z |
|
| dc.identifier |
Kyobe, J.W.M.P., Akwilapo, L. and Parmena, D.S., 2012. Theoretical Aspects of the Activation and Its Access to the Activation Energies of Gas Phase Chemical Reactions, Part I. TaJONAS: Tanzania Journal of Natural and Applied Sciences, 1(2), pp.120-137. |
|
| dc.identifier |
1821-7249 |
|
| dc.identifier |
http://hdl.handle.net/20.500.11810/3071 |
|
| dc.identifier.uri |
http://hdl.handle.net/20.500.11810/3071 |
|
| dc.description |
Full text can be accessed at
http://www.sjutpress.org/ojs/index.php/tajonas/article/view/19/25 |
|
| dc.description |
Various bonds in molecules accumulate energies under rising temperature until the energies are sufficient to promote dissociation. The activation energy of a chemical reaction AB → A + B and the bond dissociation energy, D(A-B) are calculated on the basis of the A―B bond stretching vibration ( cm-1 ). The activation energies, Ea = 883, 407, 249.31, and 437.7 kJmol-1 are calculated for nitrogen, hydrogen chloromethane and water respectively. The dissociation energies D(N-N) = 945.07, D(H-H) = 435.5, while for C2H5Cl the D(C-H) = 409.22 and D(C-Cl) = 341.75 kJmol-1 are also calculated. In each case, the theory confirms the experimental findings |
|
| dc.language |
en |
|
| dc.subject |
Vibrational energy |
|
| dc.subject |
Translational energy |
|
| dc.subject |
Rotational energy Dissociation temperature |
|
| dc.subject |
Degrees of freedom |
|
| dc.title |
Theoretical Aspects of The Activation and Its Access to The Activation Energies of Gas Phase Chemical Reactions |
|
| dc.type |
Journal Article |
|