| dc.creator |
Mbuna, Julius |
|
| dc.creator |
Takayanagi, Toshio |
|
| dc.creator |
Oshima, Mitsuko |
|
| dc.creator |
Motomizu, Shoji |
|
| dc.date |
2016-07-14T20:48:14Z |
|
| dc.date |
2016-07-14T20:48:14Z |
|
| dc.date |
2005-04 |
|
| dc.date.accessioned |
2018-03-27T08:54:54Z |
|
| dc.date.available |
2018-03-27T08:54:54Z |
|
| dc.identifier |
Mbuna, J., Takayanagi, T., Oshima, M. and Motomizu, S., 2005. Capillary zone electrophoretic studies of ion association between inorganic anions and tetraalkylammonium ions in aqueous–dioxane media. Journal of Chromatography A, 1069(2), pp.261-270. |
|
| dc.identifier |
http://hdl.handle.net/20.500.11810/3199 |
|
| dc.identifier |
10.1016/j.chroma.2005.02.009 · Source: PubMed |
|
| dc.identifier.uri |
http://hdl.handle.net/20.500.11810/3199 |
|
| dc.description |
Full text can be accessed at
http://www.sciencedirect.com/science/article/pii/S0021967305002499 |
|
| dc.description |
Ion association between inorganic anions and symmetrical tetraalkylammonium ions, R4N+ (R = Me, Et, Pr, n-Bu, n-Am, and 2-methyl butyl {isoamyl = iAm}) was investigated using ordinary silica capillary by capillary zone electrophoresis. An improved version of the Williams-Vigh method was used for the first time to measure the mobilities of the inorganic anions. Plots of log Kass against log dielectric constant in various media, revealed a smaller change in Kass compared to dielectric constant. These plots suggest that the Bjerrum's equation is inadequate in accounting for the associations of ions in a CZE setup. |
|
| dc.language |
en |
|
| dc.subject |
Aqueous–dioxane media |
|
| dc.subject |
Williams–Vigh method |
|
| dc.subject |
Ion association |
|
| dc.subject |
Capillary zone electrophoresis |
|
| dc.title |
Capillary zone electrophoretic studies of ion association between inorganic anions and tetraalkylammonium ions in aqueous-dioxane media |
|
| dc.type |
Journal Article |
|